Hi everyone, does anyone know how I can withdraw my entire PF amount before my last working day after resignation?

You cannot.

Ultimatics access not required to transfer after once left the organisation then within 3 months go to UAN portal and transfer your tcs amount into next pf account
Choose option account two into one option is there for transfer amount
For more information you can search on yotube how to transfer pf amount previous organisation into new organisation.

On parent health condition you can take money 37000 as per policy